Oxyboration with and without a Catalyst: Borylated Isoxazoles via B–O σ-Bond Addition
نویسندگان
چکیده
منابع مشابه
Oxyboration with and without a Catalyst: Borylated Isoxazoles via B–O σ-Bond Addition
Herein we report an oxyboration reaction with activated substrates that employs B-O σ bond additions to C-C π bonds to form borylated isoxazoles, which are potential building blocks for drug discovery. Although this reaction can be effectively catalyzed by gold, it is the first example of uncatalyzed oxyboration of C-C π bonds by B-O σ bonds--and only the second example that is catalyzed. This ...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2016
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.5b03530